They can usually be seen dressed comfortably while tending to their three young children together.
But Alec and Hilaria Baldwin showed that they scrub up nice.
The power couple led the attendees at the Stella McCartney Resort 2018 presentation in New York on Wednesday evening.
Though the 59-year-old 30 Rock star has the veteran acting career it was his younger 33-year-old wife who stole the show.
The yoga enthusiast put on quite the eye-popping display in a low cut black gown which showed off her ample cleavage.
She accessorized the look with a black designer bag draped over her shoulder while posing with iPhone in hand.
Alec kept his look simple in a black suit over a grey shirt with the top few buttons undone.
He teamed the look with a pair of black leather loafers as his grey locks were combed into a side-part.
The star who has had a career resurgence impersonating Donald Trump on SNL seemed to be quite the gent as he appeared to be holding onto Hilaria’s coat for her.
The couple share three children together: three-year-old daughter Carmen along with sons Rafael, one, and eight-month-old Leonardo.
Alec also posed with the woman of the hour, Stella McCartney, who wowed in a navy blue jumpsuit which she designed.
Also at the gala event was Lily Collins who perfectly encapsulated mod style in a patterned long-sleeved mini.
Her brunette tresses were worn down in a middle part as she let her natural looks show with minimal make-up.
She also had a bit of fun with her 45-year-old designer friend as they took selfies together.